Flow injection potentiometric determination of Fe(III) using a fluoride-selective electrode as detector
نویسندگان
چکیده
منابع مشابه
Flow injection potentiometric determination of Fe ( III ) using a fluoride - selective electrode as detector *
Flow injection analysis (FIA) system incorporating a fluoride ion-selective electrode (FISE) as detector is described. Laboratory-built cascade flow cell equipped with FISE and reference electrode is used for flow injection potentiometric determination of Fe(III) based on monitoring of the formation of FeF2 in acid solution. Under optimized flow conditions (4.0 mL min–1, 300 μL samples, 10–5 mo...
متن کاملSequential flow injection determination of chlorine species using a triiodide-selective electrode detector.
A flow injection analysis (FIA) method for the determination of four residual chlorine species, namely combined available chlorine (CAC), free available chlorine (FAC), total available chlorine (TAC) and chlorite (ClO2-) was developed using a flow-through triiodide-selective electrode as a detector. An important strategy of speciation studies utilized the kinetic discrimination of reactions bet...
متن کاملOn-line flow injection solid sample introduction, leaching and potentiometric determination of fluoride in phosphate rock.
A flow injection method with on-line solid sample dissolution was developed for the determination of fluoride in phosphate rock. The fluoride was selectively leached (98-102.4 % recovery) from a 50-mg powdered phosphate rock sample with 0.50 M citric acid. Using the zone sampling technique the fluoride in the buffered leachate was determined by injecting 87 muL into the carrier stream using a f...
متن کاملDetermination of Fluoride in Various Samples and Some Infusions Using a Fluoride Selective Electrode
Introduction Fluoride (F−) is an important anion, present in various environmental, clinical and food samples. Small amounts of fluoride are vital for the human organism, but it is toxic in larger amounts. For adults the lethal dose is 0.20–0.35 g F− per kg body weight. Fluoride is widely used in various branches of industry and some fluoride compounds are formed as by-products in certain proce...
متن کاملFlow injection analysis of picric acid explosive using a copper electrode as electrochemical detector.
A simple and fast electrochemical method for quantitative analysis of picric acid explosive (nitro-explosive) based on its electrochemical reduction at copper surfaces is reported. To achieve a higher sample throughput, the electrochemical sensor was adapted in a flow injection system. Under optimal experimental conditions, the peak current response increases linearly with picric acid concentra...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Analusis
سال: 1999
ISSN: 0365-4877,1286-482X
DOI: 10.1051/analusis:1999106